可张孔曝气器曝气能耗试验研究

通过试验研究，总结出可张孔曝气阻力损失的影响因素，以优化产品的结构设计参数，降低产品在工程应用中的能耗，获取更好的经济效益。     

Effects of calcination temperature on physicochemical property and activity of CuSO4/TiO2 ammonia-selective catalytic reduction catalysts

CuSO_4/TiO_2 catalysts with high catalytic activity and excellent resistant to SO_2 and H_2 O,were thought to be promising catalysts used in Selective catalytic reduction of nitrogen oxides by NH_3.The performance of catalysts is largely affected by calcination temperature.Here,effects of calcination temperature on physicochemical property and catalytic activity of CuSO_4/TiO_2 catalysts were investigated in depth.Catalyst samples calcined at different temperatures were prepared first and then physicochemical properties of the catalyst were characterized by N2 adsorption-desorption,X-ray diffraction,thermogravimetric analysis,Raman spectra,Fourier-transform infrared spectroscopy,X-ray photoelectron spectroscopy,temperature-pro grammed desorption of NH_3,temperature-programmed reduction of H_2 and in situ diffuse reflectance infrared Fourier transform spectroscopy.Results revealed that high calcination temperature had three main effects on the catalyst.First,sintering and anatase transform into rutile with increase of calcination temperature,causing a decrement of specific surface area.Second,decomposition of CuSO_4 under higher calcination temperature,resulting in disappears of Br(?)nsted acid sites(S-OH),which had an adverse effect on surface acidity.Third,CuO from the decomposition of CuSO_4 changed surface reducibility of the catalyst and favored the process of NH_3 oxidation to nitrogen oxides(NO_x).Thus,catalytic activity of the catalyst calcined under high temperatures(≥600℃) decreased largely.     

矿山排水污染稻田土壤胶体对砷的吸附研究

为研究矿山排水污染土壤胶体对砷的吸附影响,文章以高砷污染区和背景区土壤的胶体在不同的pH、离子强度以及好氧/厌氧淹水条件下对As(Ⅴ)的吸附进行对比试验。结果表明:土壤胶体对As(Ⅴ)的吸附量随pH的增大而减少,且污染区胶体比背景区胶体对As(Ⅴ)的吸附量大;离子强度越大,胶体对As(Ⅴ)的吸附量越大,Ca(NO_3)_2浓度从0.001 mol/L增至0.1 mol/L时,污染区与背景区胶体对As(Ⅴ)的吸附量分别增加了30.57%、50.25%;厌氧淹水后的胶体对As(Ⅴ)的吸附量低于好氧条件下的胶体,解吸量较高,且厌氧淹水后污染区胶体与背景区胶体相比无明显吸附优势,而好氧条件下污染区胶体的解吸率低于背景区胶体,说明厌氧淹水后的胶体不易吸附且易释放As(Ⅴ)。因此,低p H和高离子强度以及好氧的条件有利于土壤胶体对砷的吸附。     

构树修复对重金属污染土壤环境质量的影响

通过温室盆栽试验,研究构树（Broussonetia papyrifera）生长对重金属污染土壤酶活性和微生物群落结构的影响.结果表明,构树修复污染土壤中酶活性和微生物多样性明显提高.经270d培养后,构树生长土壤中蔗糖酶和酸性磷酸酶活性与种植土壤相比分别显著（P<0.05）提高3.12倍和2.29倍;土壤脱氢酶与有效态As、Cd、Pb、Zn和Cu含量,蔗糖酶与有效态Cd含量,以及磷酸酶与有效态Cd和Cu含量之间呈显著负相关（P<0.05）.根据16S和18S rDNA PCR-DGGE分析表明,构树修复可提高污染土壤中细菌和丛枝菌根真菌多样性.上述结果表明,构树修复可有效改善重金属污染土壤的环境质量.然而,污染土壤中重金属有效态含量下降不明显,必须辅助物理和化学措施来强化构树对重金属污染土壤的生态修复潜力.     

油罐铁的硫化物"自燃"危害及防护措施

分析了铁的硫化物的危害特性，阐述了硫化物“自燃”产生的热量是造成油罐发生火灾事故的主要原因，并提出了相应的防护措施，提高油罐日常使用的安全可靠性。     

煤矿风井轴流风机噪声控制设计计算

煤矿风井轴流风机气流速度大,扩散口噪声辐射强度高达113dB(A),降噪难度较大的低频成份突出。正确合理的低频噪声控制设计计算是噪声控制成功的关键。     

呼伦湖自净功能及其在区域环境保护中的作用分析

在大量详实资料和调查基础上,论述了呼伦湖富营养化状况,找出了该湖富营养化的影响因素,以及其较强自净功能的成因。呼伦湖地处内陆区高纬度、半干旱气候地区,属牧业污染型,氮入湖量主要来源于点源污染(河流的输入),磷入湖量面源(主要是降尘)大于点源。经多年观测发现,氮和磷的变化并不明显,反映出湖体有较强的自净功能,这是和湖体特殊的地理位置分不开的:①该湖系构造湖与河流沟通的吞吐湖,面积大,水较深,使得湖体自净功能显著;②地处高纬度、半干旱地区,气温低,对湖体浮游生物有一定的抑制作用;③湖体构造特殊,露出30余个泉点,有大量地下水的补给。呼伦湖是一个较大的水体与其周围湿地构成的淡水湖泊生态系统,在维持生物多样性和丰富的生物资源方面发挥巨大作用,且有明显的调蓄洪水的功能,在区域环境保护中具有特殊的地位。     

兰州市城市生活垃圾处理研究

城市生活垃圾是指在城市日常生活中或者为城市日常生活提供服务的活动中产生的固体废物以及法律、行政规定视为城市生活垃圾的固体废弃物.随着中国城市化进程的加快和人民生活水平的提高,城市生活垃圾也在以每年8%～10%的速度增长,若垃圾问题得不到妥善解决,就会制约兰州市的发展.在对兰州市城市生活垃圾处理现状及存在问题分析的基础上,根据兰州市生活垃圾的特性,提出兰州市城市生活垃圾的处理办法:兰州市城市生活垃圾应当推行分类收集制度,由目前单一的卫生填埋处理走向资源化综合处理.     

新型二氧化铅电极处理染料废水

利用高压塑片法制备掺杂镧和活性炭以及聚四氟乙烯(PTFE)的新型二氧化铅电极,采用X衍射(XRD),循环伏安曲线(CV),扫描电镜(SEM)等手段对电极性能进行表征,研究了其电催化处理有机染料废水(亚甲基蓝)的降解效果,并对反应机理进行了相关研究。研究表明,该电极具有良好的抗腐蚀能力,对亚甲基蓝具有较好的降解效果。通过与普通二氧化铅电极比较,该电极在染料脱色和去除COD方面都有较明显优势,显示出较好的工业应用前景。     

Performance of IUCN proxies for generation length

One of the criteria used by the International Union for Conservation of Nature (IUCN) to assess threat status is the rate of decline in abundance over 3 generations or 10 years, whichever is longer. The traditional method for calculating generation length (T) uses age‐specific survival and fecundity, but these data are rarely available. Consequently, proxies that require less information are often used, which introduces potential biases. The IUCN recommends 2 proxies based on adult mortality rate, = α + 1/d, and reproductive life span, = α + z^*RL, where α is age at first reproduction, d is adult mortality rate, RL is reproductive life span, and z is a coefficient derived from data for comparable species. We used published life tables for 78 animal and plant populations to evaluate precision and bias of these proxies by comparing and with true generation length. Mean error rates in estimating T were 31% for and 20% for , but error rates for were 16% when we subtracted 1 year ( ), as suggested by theory; also provided largely unbiased estimates regardless of the true generation length. Performance of depends on compilation of detailed data for comparable species, but our results suggest taxonomy is not a reliable indicator of comparability. All 3 proxies depend heavily on a reliable estimate of age at first reproduction, as we illustrated with 2 test species. The relatively large mean errors for all proxies emphasized the importance of collecting the detailed life‐history information necessary to calculate true generation length. Unfortunately, publication of such data is less common than it was decades ago. We identified generic patterns of age‐specific change in vital rates that can be used to predict expected patterns of bias from applying .